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An electrolyte salt as an alkali metal (e.g., sodium or potassium) chloride may be present (e.g., 1 to 1000 ppm) in the stable remineralizing solution to further improve stability and diffusion of remineralizing material into subsurface lesions.

Acidic materials are used to reduce the p H to about 2-4, typically about 2.8-3.8, in order to maintain clarity of the solution.

The ratio of calcium ion to phosphate ion may be from about 0.01 to about 100:1, but is desirably about 1.67:1 in order to optimally form hydroxyapatite, for instance using about 1.5 m M calcium ion and 0.9 m M phosphate ion in solution.

A preservative such as sodium benzoate or methyl-4-hydroxybenzoate may be employed to reduce bacterial growth.

For instance, in the case of a fluoride source of low solubility, such as calcium fluoride, the amount of the compound employed should not exceed 15000 ppm. For instance, such insoluble crystals form when it is sought to use antinucleating agents such as sodium hexametaphosphate, sodium pyrophosphate, sodium phytate and mellitic acid as well as disodiumphosphonoethane-1,2-dicarboxylate, 1,1-diphosphonopropane-2,3-dicarboxylic acid monohydrate, 3-amino-1-hydroxypropane-1,1-diphosphonic acid and imino diacetic-N-methylene phosphonic acid. The normally insoluble sources of calcium and phosphate ions may be a single compound such as tricalcium phosphate (which substantially corresponds to hydroxyapatite, Ca, bone meal or dicalcium phosphate (dihydrate or anhydrous). It has been found that not all antinucleating agents can successfully stabilize calcium ions and phosphate ions against precipitating to form large insoluble apatite crystals. When the source is normally insoluble such as a calcium phosphate, it is solubilized during preparation of the solution, by maintaining an acid p H of about 6 or less (e.g., about 2.5 to 6) during preparation of the remineralizing solution, particularly before the effective antinucleating agent is added.Sodium fluoride and sodium monofluorophosphate are preferred.The fluoride source compound is desirably present in amount to provide about 1 ppm to 10,000 ppm (0.0001%-1%) fluoride to the remineralizing dentifrice e.g., about 1 ppm to 1000 ppm (0.0001-0.76%) sodium monofluorophosphate, preferably about 5 ppm fluoride.

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